I'm not much good at framing (yet?) but good at asking questions - well I suppose the forum needs both sorts

Firstly, I painted a frame with some coats of ripple paint as undercoat, then dark violet acrylic (mixture of blue,red,black) - but with only minimal handling some bits of white are showing, so I'm wondering two things:
1) I didn't need to fill the grain (ie: using filler/ripple paint) so should I have simply used two or three coats of the acrylic topcoat, or is there a recommended base coat (if so what is best colour for light/dark topcoat)
2) Maybe the acrylic I've used is not best quality. I bought some 500ml tubs from a fairly well known, small supplier with no makers name on them, at a cost of just over a fiver each, and it did seem a little on the thin side. I see some use Everest paint from Lion, but looks pricey to me. Can anyone recommend a decent, fairly priced acrylic, or maybe emulsion from Wickes etc is ok (but would prefer some basic primary colour so I could mix, which I don't think Wickes etc would do?)
Another thing is that I painted the frame after it was made up, and although the paint looks pretty good, even for me, the build up in the corners is not so pleasing. I have a couple of questions on this please:
1) Someone on the forum said that after painting, to give a nice smooth finish, they finish with a mixture of something like meths + 5% acetone rubbed onto the paint with a rag - I'm wondering if corners could be improved with this method, and rubbing the mixture a little more into the corners to reduce the paint build up?
2) I would prefer to make the frame before painting etc as I've had a couple of frames that were wonky and needing a little bit of filler and sanding on the corners. My worry is that if I painted before making the frame, then found the corners weren't great, it would be too late. Any preferences?
3) I know it's usual to sometimes run a marker pen on the mitres so the light wood doesn't show on a less than perfect join - I'm wondering whether anyone uses a little acrylic (ie: if using bright yellow paint for the frame, could you use just a little on the mitres?)
Also, Wessex are about an hour from me, and wonder what their mouldings are like - just want to ensure I usually get decent straight mouldings
Many thanks