Dermot wrote:
For my sin in another life I sold polymer test equipment….I got to know the polymer industry quite well……….I still subscribe to one of the main polymer publications
Most of the products I currently sell in my business are made of polymers…..some of which I spec into the electronics and heath care manufacturing sectors…….out gassing with most plastics is not a problem…..
……..for the life of me I’m trying to figure out what plastic materials either moulding, glazing or encapsulation that could or are used in the picture framing industry out gas……perhaps you could enlighten me!!!!!......and point me in the direction of the studied that support your statement…
The subject of adhesives is an entirely separate, science and subject, to plastics and to equate the possible situations with adhesives and plastics that are or can be used in the picture framing industry is a bit disingenuous….
O.K. Dermot,
I am not a polymers expert like you self and I could have been a little bit smarter how I worded it, but I did ask the question "where does the escaping plasticiser go and can it affect the conservation of the artwork?" because I don't know and was trying to contribute to the thread by asking.
You have now answered that question because you do know. In you doing so, I and I trust others have learnt something helpful to know.
My comments about plasticisers come from my experiences as a design engineer. As a young engineer, I was taught that the instablility and failure issues with polymers were mainly related to: Long term loss of plasticisers (some polymers are better than others), ultra-voilet, visible light, heat and other forms of electro-magnetic radiation, mechanical and thermal stress issues and storage and operating environmental temperatures. As you can see, whilst I am not a polymers expert, I am well versed in engineering materials issues.
Many products had to have design changes due to lessons learnt from failures due the life and use of product, where things which should not break did so and self adhesives which should not fail also did so. Such items were returned for analysis and in many cases loss of plasticisers was a favorite expaination. Whether this was just a expedient excuse or always correct, it was a commonly offered explaination.
As these plasticisers contain at least some chemical compounds which are publically said by the media to cause environmental problems because they don't break down they must therefore somehow escape from the plastics in their existing form instead of breaking down. As I have just said, I am not an expert, but I think it is likely that "escape, disperse or out-gas" covers most if not all possiblities and as you will note from my original question "where does the escaping plasticiser go", I am happy to be advised by and to learn from those who know better such as yourself.
Next time I think I'll think more carefully what I have to say!